Percolation theory applied in modelling of Fe2O3 reduction during chemical looping combustion

نویسندگان

چکیده

The study presents a new modelling approach applied to hematite magnetite reduction, which is the dominant reaction in atmospheres with high CO2/CO ratio, expected chemical looping combustion. structure of Fe2O3 particle was simulated using percolation theory, while reduction modelled stochastic simulate nucleation, gaseous diffusion, solid-state and reaction. To account for differences between 3-D 2-D pores, model allowed pore-hopping. obtained results agreed experimental derived from natural ore (pyrite), and, lesser extent, lab-synthesised particles. provides useful insight into complexity investigated process. For materials undeveloped porosity, simple shrinking-core approximation will be sufficient. In contrast, well-developed models should incorporate information about structure.

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ژورنال

عنوان ژورنال: Chemical Engineering Journal

سال: 2021

ISSN: ['1873-3212', '1385-8947']

DOI: https://doi.org/10.1016/j.cej.2020.126845